Jo, Hanju Ko, Jieun Lim, Jung Ah Chang, Hye Jung Kim, Youn Sang 2024-01-20T13:01:31Z 2024-01-20T13:01:31Z 2021-09-01 2013-02-25 1022-1336 https://pubs.kist.re.kr/handle/201004/128346 Organic nonvolatile resistive switching memory is developed via selective incorporation of fullerene derivatives, [6,6]-phenyl-C61 butyric acid methyl ester (PCBM), into the nanostructure of self-assembled poly(styrene-b-methyl methacrylate) (PS10-b-PMMA130) diblock copolymer. PS10-b-PMMA130 diblock copolymer provides a spatially ordered nanotemplate with a 10-nm PS nanosphere domain surrounded by a PMMA matrix. Spin casting of the blend solution of PS10-b-PMMA130 and PCBM spontaneously forms smooth films without PCBM aggregation in which PCBM molecules are incorporated within a PS nanosphere domain of PS10-b-PMMA130 nanostructure by preferential intermixing propensity of PCBM and PS. Based on the well-defined PS10-b-PMMA130/PCBM nanostructure, resistive random access memory (ReRAM) exhibits significantly improved bipolar-switching behavior with stable and reproducible properties at low operating voltages (RESET at 1.3 V and SET at 1.5 V) under ambient conditions. Finally, flexible memory devices are achieved using a nanostructured PS10-b-PMMA130/PCBM composite in which no significant degradation of electrical properties is observed before and after bending. English WILEY-V C H VERLAG GMBH DEVICE APPLICATIONS FLEXIBLE SUBSTRATE THIN-FILM POLYMER ELECTRONICS TRANSISTORS MECHANISMS TRANSPORT LAYER OXIDE Organic Nonvolatile Resistive Switching Memory Based on Molecularly Entrapped Fullerene Derivative within a Diblock Copolymer Nanostructure Article 10.1002/marc.201200614 1 MACROMOLECULAR RAPID COMMUNICATIONS, v.34, no.4, pp.355 - 361 MACROMOLECULAR RAPID COMMUNICATIONS 34 4 355 361 scie scopus 000314993900008 2-s2.0-84873891844 Polymer Science Polymer Science Article DEVICE APPLICATIONS FLEXIBLE SUBSTRATE THIN-FILM POLYMER ELECTRONICS TRANSISTORS MECHANISMS TRANSPORT LAYER OXIDE block copolymer flexible memory fullerene derivative information storage material resistive switching memory