Jung, Dong Eui Han, Joon Soo Yoo, Bok Ryul 2024-01-20T13:03:33Z 2024-01-20T13:03:33Z 2021-09-01 2013-01-15 0022-328X https://pubs.kist.re.kr/handle/201004/128448 The thermal reactions of trichlorosilane (1a) with cyclic alkadienes such as cyclopentadiene (2a), 1,3-cyclohexadiene (2b), and 1,4-cyclohexadiene (2c) were studied at temperatures ranging from 170 degrees C to 250 degrees C. In this reaction, the hydrosilylation rate increased as the reaction temperature was raised using an equimolar ratio of 1a to 2a. The reaction of 2a with 1a at 250 degrees C afforded 2-cyclopentenyltrichlorosilane (3a) as the major hydrosilylation product within 1 h in good yield (82%). This reaction also works when dicyclopentadiene (2a&apos;) was used as a reactant instead of 2a. In a large scale preparation under the same conditions, 3a was obtained in 82% isolated yield. It is significant to note that 2a&apos; can be used for the hydrosilylation, with no requirement of a cracking step under our thermal conditions. While the reaction of cyclohexadienes with 1a under the same conditions gave a mixture of three hydrosilylation products such as 2-cyclohexenyltrichlorosilane (3b), 3-cyclohexenyltrichlorosilane (3c) and cyclohexyltrichlorosilane (5) in moderate yields, along with other unsaturated C6 components, such as benzene and cyclohexene. In the thermal reaction of cycloalkadienes with 1a, the five-membered-ring diene 2a undergoes both a hydrosilylation reaction with 1a as well as a [4 + 2] cycloaddition reaction, leading to the hydrosilylation product 3a in good yield. While the six-membered ring dienes, 2b and 2c, undergo four different types of reactions, including hydrosilylation, [4 + 2] cycloaddition, dehydrogenation, and hydrogenation in competition to give the hydrosilylation products, hexane, and benzene, respectively. The reaction rates of cyclic alkadienes under our thermal conditions increase in the following order: 2c << 2b < 2a. (C) 2012 Elsevier B. V. All rights reserved. English ELSEVIER SCIENCE SA SILICON HYDROSILYLATION Thermal reaction of cyclic alkadiene with trichlorosilane. Preparative and mechanistic aspects Article 10.1016/j.jorganchem.2012.10.015 1 JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.724, pp.40 - 44 JOURNAL OF ORGANOMETALLIC CHEMISTRY 724 40 44 scie scopus 000314113400006 2-s2.0-84869863266 Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry Article SILICON HYDROSILYLATION Hydrosilylation Thermal reaction Cycloalkadiene Hydrosilane Trichlorosilane Cycloalkenyltrichlorosilane