Nugroho, Agung Kim, Su Jin Chung, Kyung Yoon Kim, Jaehoon 2024-01-20T14:02:21Z 2024-01-20T14:02:21Z 2021-09-05 2012-09-01 0013-4686 https://pubs.kist.re.kr/handle/201004/128880 Nanosized and highly crystalline spinel lithium titanium oxide (Li4Ti5O12, LTO) particles are synthesized in supercritical water. The effects of various synthesis conditions - feed concentration, reaction time, and calcination - on the particle properties, including particle size, surface area, particle morphology, phase purity, and crystallinity, are carefully analyzed. Phase-pure LTO particles are obtained with a long reaction time of 6h in supercritical water at 400 degrees C and 300 bar without subsequent calcination, while the anatase TiO2 impurity phase is detected at shorter reaction times of 5 min to 2 h. Particles synthesize in supercritical water with subsequent calcination at a relatively low temperature of 700 degrees C exhibit the highly crystalline LTO phase. Based on the analytical results using scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), and X-ray diffraction (XRD), an LTO formation mechanism in supercritical water is proposed. LTO particles prepare in supercritical water with subsequent calcination exhibit excellent long-term cyclability and high-rate performance. The discharge capacity after 400 cycles at 1C is 117.2 mAh g(-1), which is approximately 80% of the initial discharge capacity (147.1 mAh g(-1)), and the discharge capacity at 10C is 100.5 mAh g(-1). These electrochemical performances are significantly better than those of uncalcinated LTO synthesize in supercritical water and solid-state synthesize LTO. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved. English PERGAMON-ELSEVIER SCIENCE LTD CONTINUOUS HYDROTHERMAL SYNTHESIS NANOSIZED LI4TI5O12 FACILE SYNTHESIS SPINEL PARTICLES ELECTRODES INSERTION NANOPARTICLES CELLS ANODE Synthesis of Li4Ti5O12 in supercritical water for Li-ion batteries: Reaction mechanism and high-rate performance Article 10.1016/j.electacta.2012.06.060 1 ELECTROCHIMICA ACTA, v.78, pp.623 - 632 ELECTROCHIMICA ACTA 78 623 632 scie scopus 000308259500084 2-s2.0-84864280976 Electrochemistry Electrochemistry Article CONTINUOUS HYDROTHERMAL SYNTHESIS NANOSIZED LI4TI5O12 FACILE SYNTHESIS SPINEL PARTICLES ELECTRODES INSERTION NANOPARTICLES CELLS ANODE Lithium titanium oxide Supercritical water Anode materials Lithium secondary batteries