안기용 정용재 이종호 2024-01-20T14:04:54Z 2024-01-20T14:04:54Z 2021-09-06 2012-08 1738-7264 https://pubs.kist.re.kr/handle/201004/129008 The properties of methane oxidation were studied in this research over transition metal containing CeO2 (TM/CeO2, TM=Ni, Co, Cu, Fe) with TM content of 5 wt. % at atmospheric pressure. The characteristics of catalysts were investigated by various characterization techniques, including XRD, GC, SEM and EPMA analyses. The catalytic tests were carried out in a fixed Rmix ratio of 1.5 (CH4/O2) in a fixed-bed reactor operating isothermally at atmospheric pressure. Only the Ni/CeO2 catalysts showed syngas production above 400℃ via typical partial oxidation reaction whereas other catalysts induced complete oxidation resulting in the production of CO2 and H2O in whole reaction temperature range. From the quantitative analysis on carbon deposition after catalytic tests, Cu/CeO2 was found to show the highest resistance on carbon deposition. Therefore Cu can be proposed as an efficient catalyst element which can be combined with a conventional Ni-based SOFC anode to enhance the carbon tolerance. Korean 한국수소및신에너지학회 전이금속이 담지된 세리아의 메탄 산화 반응에 대한 연구 A Study of Methane Oxidation over Transition Metal (TM)/CeO2 (TM=Ni, Co, Cu, Fe) Article 10.7316/KHNES.2012.23.4.346 2 한국수소및신에너지학회논문집, v.23, no.4, pp.346 - 352 한국수소및신에너지학회논문집 23 4 346 352 kci ART001693336 Nickel Ceramic Carbon deposition Methane Gas chromatography 니켈 세라믹 탄소 흡착 메탄 가스 크로마토그래프