Noh, Yunyoung Yu, Byungkwan Yoo, Kicheon Ko, Min Jae Song, Ohsung 2024-01-20T15:06:15Z 2024-01-20T15:06:15Z 2021-09-04 2012-03 1738-8228 https://pubs.kist.re.kr/handle/201004/129503 A ruthenium (Ru) catalytic layer and a conventional Pt layer were assessed as counter electrodes (CE) for dye sensitized solar cells (DSSCs). Ru films with different thicknesses of 34, 46, and 90 nm were deposited by atomic layer deposition (ALD). Pt layers with the same thicknesses were prepared by sputtering. 0.45 cm(2) DSSCs were prepared and their properties were characterized by FE-SEM, cyclic voltammetry (CV), impedance spectroscopy (EIS), and current-voltage (I-V). FE-SEM revealed that the crystallized Ru films and Pt films had been deposited quite conformally. CV showed that the catalytic activity of Pt was much greater than that of Ru. In addition, although the catalytic activity of Pt did not depend on the thickness, that of Ru showed an increase with increasing thickness. Impedance analysis revealed high charge transfer resistance at the Ru interface and a decrease with increasing Ru thickness, whereas Pt showed low resistance with no thickness dependence. Despite the relatively small catalytic activity of Ru, the I-V result revealed the average energy conversion efficiency of Ru and Pt to be 2.98% and 6.57%, respectively. These results suggest that Ru can be used as counter electrodes in DSSCs due to its extremely low temperature process compatibility. Korean KOREAN INST METALS MATERIALS ATOMIC LAYER DEPOSITION RUTHENIUM PERFORMANCE PLATINUM OXIDE Property of Counter Electrode with Pt and Ru Catalyst Films for Dye-Sensitized Solar Cell Article 10.3365/KJMM.2012.50.3.243 1 KOREAN JOURNAL OF METALS AND MATERIALS, v.50, no.3, pp.243 - 247 KOREAN JOURNAL OF METALS AND MATERIALS 50 3 243 247 scie scopus kci ART001643264 000302048200009 2-s2.0-84860109597 Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Materials Science Metallurgy & Metallurgical Engineering Article ATOMIC LAYER DEPOSITION RUTHENIUM PERFORMANCE PLATINUM OXIDE solar cells sputter optical properties nano electrode