Lee, Yun Ju Hong, Suk-In Moon, Dong Ju 2024-01-20T16:03:50Z 2024-01-20T16:03:50Z 2021-09-04 2011-10-02 0920-5861 https://pubs.kist.re.kr/handle/201004/129901 Steam CO2 reforming (SCR) of methane for the production of syngas was simulated using PRO-II and investigated over Ni-based catalysts for GTL-FPSO applications. The Ni-based catalysts were prepared by an impregnation method. The catalysts before and after the reaction were characterized by N-2 physisorption, XRD and TEM techniques. The conversion of CH4 was increased by increasing the concentration of H2O and CO2 in the feed. For the application in Co-based Fischer-Tropsch synthesis, the synthesis gas ratio of H-2/CO = 1.85-2.0 in the SCR was designed by the modeling of PRO-II simulator, and identified in a fixed bed reactor system by controlling the feed molar ratios of CH4:H2O:CO2. It was found that Ni/MgO catalyst is more desirable catalyst for the production of synthesis gas than Ni/gamma-Al2O3 and Ru/TiO2 catalysts on the point of the low carbon formation and suitable H-2/CO ratio for the GTL-FPSO applications with Co-based FT process. (C) 2011 Published by Elsevier B.V. English ELSEVIER FISCHER-TROPSCH SYNTHESIS PARTIAL OXIDATION GAS CATALYST SUPPORT SYNGAS NI Studies on the steam and CO2 reforming of methane for GTL-FPSO applications Article 10.1016/j.cattod.2011.04.031 1 CATALYSIS TODAY, v.174, no.1, pp.31 - 36 CATALYSIS TODAY 174 1 31 36 scie scopus 000294304600006 2-s2.0-80052262246 Chemistry, Applied Chemistry, Physical Engineering, Chemical Chemistry Engineering Article; Proceedings Paper FISCHER-TROPSCH SYNTHESIS PARTIAL OXIDATION GAS CATALYST SUPPORT SYNGAS NI Methane Steam CO2 reforming Simulation Syngas GTL GTL-FPSO