Han, Won-Sik Kim, Tae-Jin Kim, Sung-Kwan Kim, Yongmin Kim, Yeongcheon Nam, Suk-Woo Kang, Sang Ook 2024-01-20T16:30:57Z 2024-01-20T16:30:57Z 2021-09-05 2011-09 0360-3199 https://pubs.kist.re.kr/handle/201004/130014 A series of cyclic- and linear organosilanes, 1-5, was prepared and examined as potential hydrogen storage materials. When a stoichiometric amount of methanol was added to a mixture of cyclic organosilane, (CH2SiH2)(3) (1) or (CH2SiH2CHSiH3)(2) (2), and 5 mol%NaOMe, rapid hydrogen release was observed at room temperature within 10-15 s. The hydrogen storage capacities of compounds 1 and 2 were estimated to be 3.70 and 4.04 wt.-% H-2, respectively. However, to ensure the complete methanolysis from organosilanes including methanol evaporation at exothermic dehydrogenation condition, two equivs of methanol were used. The resulting methoxysilanes, (CH2Si(OMe)(2))(3) (6) and (CH2Si(OMe)(2)CHSi(OMe)(3))(2) (7), were regenerated to the starting organosilanes in high yields by LiAlH4 reduction. Linear organosilanes, SiH3CH2SiH2CH2SiH3 (3), SiH3CH2CH(SiH3)(2) (4), and SiH3CH2CH(SiH3) CH2SiH3 (5) also showed fast hydrogen release kinetics at room temperature with hydrogen storage capacities of 4.26, 4.55, and 4.27 wt.% H-2, respectively; the corresponding methoxysilanes were successfully regenerated by LiAlH4. Compound 1 was further tested as hydrogen source for fuel cell operation. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. English PERGAMON-ELSEVIER SCIENCE LTD BOROHYDRIDE SOLUTION AMMONIA-BORANE GENERATION HYDROLYSIS CATALYST ALCOHOLYSIS MECHANISM BORON Silane-based hydrogen storage materials for fuel cell application: Hydrogen release via methanolysis and regeneration by hydride reduction from organosilanes Article 10.1016/j.ijhydene.2011.06.118 1 INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v.36, no.19, pp.12305 - 12312 INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 36 19 12305 12312 scie scopus 000295657300025 2-s2.0-80052796441 Chemistry, Physical Electrochemistry Energy & Fuels Chemistry Electrochemistry Energy & Fuels Article BOROHYDRIDE SOLUTION AMMONIA-BORANE GENERATION HYDROLYSIS CATALYST ALCOHOLYSIS MECHANISM BORON Hydrosilane Hydrogen storage material Regeneration PEMFC