Lim, Chang-Keun Seo, Jangwon Kim, Sehoon Kwon, Ick Chan Ahn, Cheol-Hee Park, Soo Young 2024-01-20T16:31:28Z 2024-01-20T16:31:28Z 2021-09-05 2011-09 0143-7208 https://pubs.kist.re.kr/handle/201004/130040 A dual-emissive biopolymeric amphiphile (GC-HBO) has been prepared by densely conjugating hydrophilic glycol chitosan (GC) with a phototautomerizable hydrophobic dye (a derivative of 2-(2'-hydroxyphenyl) benzoxazole, HBO) showing excited-state intramolecular proton transfer (ESIPT). Ratiometric modulation of phototautomeric (enol-keto) dual emission, governed by the chromophoric aggregation state, was studied with a low-molecular-weight model compound (GA-HBO) and was well correlated with the nanoparticle-forming behavior of GC-HBO via amphiphilic self-assembly in water. It has been found that the promoted chromophoric aggregation at higher concentration or at basic-to-neutral pH assists the nanostructure formation to generate predominant keto emission while the enol emission is intensified at lower concentration or with decreasing pH by disintegration of self-assembled structure. The assembly-related advantageous potential of GC-HBO for probing self-concentration and surrounding pH has been demonstrated with the ratiometric determination of critical particulation concentration (0.04 kg m(-3)) and near-physiological pH sensitivity (pK(a) similar to 5.1). (C) 2011 Elsevier Ltd. All rights reserved. English ELSEVIER SCI LTD INTRAMOLECULAR PROTON-TRANSFER GLYCOL CHITOSAN NANOPARTICLES ORGANIC NANOPARTICLES EMISSION STATE 2-(2&apos -HYDROXYPHENYL)BENZOXAZOLE SYSTEM PROBE Concentration and pH-modulated dual fluorescence in self-assembled nanoparticles of phototautomerizable biopolymeric amphiphile Article 10.1016/j.dyepig.2010.12.014 1 DYES AND PIGMENTS, v.90, no.3, pp.284 - 289 DYES AND PIGMENTS 90 3 284 289 scie scopus 000289125000011 2-s2.0-79952370631 Chemistry, Applied Engineering, Chemical Materials Science, Textiles Chemistry Engineering Materials Science Article INTRAMOLECULAR PROTON-TRANSFER GLYCOL CHITOSAN NANOPARTICLES ORGANIC NANOPARTICLES EMISSION STATE 2-(2&apos -HYDROXYPHENYL)BENZOXAZOLE SYSTEM PROBE Excited-state intramolecular proton transfer (ESIPT) Ratiometric fluorescence sensor Fluorescent nanoparticle pH sensor Self-assembly Biopolymeric conjugate