Kim, Hyo-Joong Choi, Kwon-Il Pan, Anqiang Kim, Il-Doo Kim, Hae-Ryong Kim, Kang-Min Na, Chan Woong Cao, Guozhong Lee, Jong-Heun 2024-01-20T17:03:45Z 2024-01-20T17:03:45Z 2021-09-02 2011-05 0959-9428 https://pubs.kist.re.kr/handle/201004/130407 Magnetite (Fe3O4) hollow spheres were prepared by solvothermal reaction of ethanol solution containing Fe-acetate and L-lysine, and were subsequently transformed into hematite (Fe2O3) hollow spheres with nanoscale (20-30 nm) thin shells by heat treatment at 500 degrees C for 2 h. Both the as-prepared and heat-treated hollow spheres contained another small sphere within each shell, which was attributed to the following solvothermal self-assembly reactions: (1) the nucleation of Fe3O4 spheres, (2) lysine capping on the nuclei, (3) the growth of lysine-capped particles by cross-linking between lysine molecules, and (4) the formation of Fe shell layers by the interaction between Fe ions and outer lysine molecules. In the assembly reaction, L-lysine with amino and carboxyl radicals played the key role. The heat-treated Fe2O3 hollow spheres showed significantly enhanced C2H5OH sensing characteristics and promising Li-ion intercalation behaviors. English ROYAL SOC CHEMISTRY FORMATION MECHANISM NANOSTRUCTURES SNO2 MICROSPHERES PERFORMANCE MORPHOLOGY NANORODS STORAGE PHASE Template-free solvothermal synthesis of hollow hematite spheres and their applications in gas sensors and Li-ion batteries Article 10.1039/c0jm03516e 1 JOURNAL OF MATERIALS CHEMISTRY, v.21, no.18, pp.6549 - 6555 JOURNAL OF MATERIALS CHEMISTRY 21 18 6549 6555 scie scopus 000289692500018 2-s2.0-79955070174 Chemistry, Physical Materials Science, Multidisciplinary Chemistry Materials Science Article FORMATION MECHANISM NANOSTRUCTURES SNO2 MICROSPHERES PERFORMANCE MORPHOLOGY NANORODS STORAGE PHASE