Banerjee, Debasis Kim, Sun Jin Wu, Haohan Xu, Wenqian Borkowski, Lauren A. Li, Jing Parise, John B. 2024-01-20T18:00:30Z 2024-01-20T18:00:30Z 2021-09-02 2011-01-03 0020-1669 https://pubs.kist.re.kr/handle/201004/130736 A gallium-based metal organic framework Ga-6(C9H3O6)(8).(C2H8N)(6)(C3H7NO)(3)(H2O)(26) [1, Ga-6(1,3,5-BTC)(8).6DMA. 3DMF.26H(2)O], GaMOF-1; BTC = benzenetricarboxylate/trimesic acid and DMA = dimethylamine], with space group l (4) over bar 3d, a = 19.611(1) angstrom, and V= 7953.4(6) angstrom(3), was synthesized using solvothermal techniques and characterized by synchrotron-based X-ray microcrystal diffraction. Compound 1 contains isolated gallium tetrahedra connected by the organic linker (BTC) forming a 3,4-connected anionic porous network. Disordered positively charged ions and solvent molecules are present in the pore, compensating for the negative charge of the framework. These positively charged molecules could be exchanged with alkali-metal ions, as is evident by an ICP-MS study. The H-2 storage capacity of the parent framework is moderate with a H-2 storage capacity of similar to 0.5 wt % at 77 K and 1 atm. English AMER CHEMICAL SOC MU(3)-OXO-CENTERED TRINUCLEAR UNITS HEXAGONAL 18-RING NETWORK HIGH THERMAL-STABILITY SOLID-STATE NMR COORDINATION POLYMERS HYDROGEN STORAGE GAS-ADSORPTION 1D CHAIN MIL-96 INDIUM Anionic Gallium-Based Metal-Organic Framework and Its Sorption and Ion-Exchange Properties Article 10.1021/ic101789u 1 INORGANIC CHEMISTRY, v.50, no.1, pp.208 - 212 INORGANIC CHEMISTRY 50 1 208 212 scie scopus 000285559800024 2-s2.0-78650713790 Chemistry, Inorganic & Nuclear Chemistry Article MU(3)-OXO-CENTERED TRINUCLEAR UNITS HEXAGONAL 18-RING NETWORK HIGH THERMAL-STABILITY SOLID-STATE NMR COORDINATION POLYMERS HYDROGEN STORAGE GAS-ADSORPTION 1D CHAIN MIL-96 INDIUM MOF Gallium Ion-Exchange H2 isotherm