Kim, Sung-Kwan Han, Won-Sik Kim, Tae-Jin Kim, Tae-Young Nam, Suk Woo Mitoraj, Mariusz Piekos, Lukasz Michalak, Artur Hwang, Son-Jong Kang, Sang Ook 2024-01-20T19:01:00Z 2024-01-20T19:01:00Z 2021-09-05 2010-07-28 0002-7863 https://pubs.kist.re.kr/handle/201004/131240 Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H-2 in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations. English AMER CHEMICAL SOC METAL-PROMOTED REACTIONS BORON-NITROGEN BONDS COUPLED-CAGE BORANE AMINE-BORANE HYDRIDES AMINOBORANES COMPLEXES CARBORANE NITRIDE ROUTE Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B-H Activation Article 10.1021/ja101685u 1 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.29, pp.9954 - 9955 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132 29 9954 9955 scie scopus 000280227700008 2-s2.0-77955832702 Chemistry, Multidisciplinary Chemistry Article METAL-PROMOTED REACTIONS BORON-NITROGEN BONDS COUPLED-CAGE BORANE AMINE-BORANE HYDRIDES AMINOBORANES COMPLEXES CARBORANE NITRIDE ROUTE ammonia borane dehydrogenation Pd(II) complexes