Han, Joon Soo Sasamori, Takahiro Mizuhata, Yoshiyuki Tokitoh, Norihiro 2024-01-20T19:34:12Z 2024-01-20T19:34:12Z 2021-09-01 2010-03-03 0002-7863 https://pubs.kist.re.kr/handle/201004/131642 The reactivity of a bulky, diaryl-substituted disilyne, Ar-Si Si-Ar, was examined for the first time. Reaction of the disilyne with ethylene yielded an ethylene-bridged bis(silacyclopropane), which is interpreted as a Further reaction product of the initially formed 1,2-disilacyclobutene species with ethylene. A cyclohexane fused with a 1,2-disilacyclobutene was obtained in the reaction with cyclohexene. In the reaction with 2,3-dimethyl-1,3-butadiene, a tricyclo derivative was isolated from the complex product mixture. English AMER CHEMICAL SOC DISILYNE RSISIR R ELEMENT ALKYNE ANALOGS GERMANIUM ANALOG STABLE DISILENES MULTIPLE BONDS COMPOUND REDUCTION CHEMISTRY CHARACTER SILYLENE Reactivity of an Aryl-Substituted Silicon-Silicon Triple Bond: Reactions of a 1,2-Diaryldisilyne with Alkenes Article 10.1021/ja9108566 1 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.8, pp.2546 - + JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132 8 2546 + scie scopus 000275117900028 Chemistry, Multidisciplinary Chemistry Article DISILYNE RSISIR R ELEMENT ALKYNE ANALOGS GERMANIUM ANALOG STABLE DISILENES MULTIPLE BONDS COMPOUND REDUCTION CHEMISTRY CHARACTER SILYLENE disilyne disilene kinetic stabilization disilacyclobutene