Banerjee, Debasis Borkowski, Lauren A. Kim, Sun Jin Parise, John B. 2024-01-20T20:31:25Z 2024-01-20T20:31:25Z 2021-09-05 2009-11 1528-7483 https://pubs.kist.re.kr/handle/201004/132001 Two lithium-based metal-organic frameworks, Li-2(C14H8O4) [Li-2(4,4'-BPDC) [1]; ULMOF-2, UL = ultralight; BPDC = biphenyldicarboxylate]; space group P2(1)/c, a = 12.758(2) angstrom, b = 5.142(4) angstrom, c = 8.00(2) angstrom, beta = 97.23 degrees, V = 520.6(14) angstrom(3) and Li-2(C14H8O6S) [Li-2(4,4'-SDB) [2]; ULMOF-3, UL = ultralight; SDB = sulfonyldibenzoate], space group P2(1)/n, a = 5.5480(11) angstrom, b = 23.450(5) angstrom, c = 10.320(2) angstrom, beta = 96.47(3)degrees, V = 1334.1(5) angstrom(3), were synthesized. Compounds I and 2 were synthesized by solvothermal methods and were characterized using single crystal X-ray diffraction. Structure 1 consists of layers of two-dimensional antifluorite related LiO motif connected by BPDC linkers, whereas structure 2 is constructed by a combination of tetrameric lithium polyhedral clusters connected by the sulfonyldibenzoate linker. The frameworks are stable up to 575 and 500 degrees C, respectively, under N-2 atmosphere. English American Chemical Society HYDROGEN STORAGE MATERIALS COORDINATION POLYMER GAS-ADSORPTION CARBON-DIOXIDE PORE-SIZE SORPTION TEMPERATURE CATALYSIS CAPACITY LIGANDS Synthesis and Structural Characterization of Lithium-Based Metal-Organic Frameworks Article 10.1021/cg900705c 1 Crystal Growth & Design, v.9, no.11, pp.4922 - 4926 Crystal Growth & Design 9 11 4922 4926 scie scopus 000271272900051 2-s2.0-73049101053 Chemistry, Multidisciplinary Crystallography Materials Science, Multidisciplinary Chemistry Crystallography Materials Science Article HYDROGEN STORAGE MATERIALS COORDINATION POLYMER GAS-ADSORPTION CARBON-DIOXIDE PORE-SIZE SORPTION TEMPERATURE CATALYSIS CAPACITY LIGANDS