Kim, Cho Rong Kang, Hyun Ji Kim, Chi Won Yoo, Kyung Ho Jung, Ok-Sang 2024-01-20T20:35:23Z 2024-01-20T20:35:23Z 2021-09-05 2009-09 0340-4285 https://pubs.kist.re.kr/handle/201004/132193 The reaction of (COD)PdCl2 (COD = 1,5-cyclooctadiene) with (3-Py)(2)SiMe2 (bis(3-pyridyl)dimethylsilane) in acetone produces single crystals consisting of cyclodimers, [PdCl2((3-Py)(2)SiMe2)](2), whereas the similar reaction in a mixture of dichloromethane and ethanol yields amorphous submicrospheres consisting of cyclotrimers, [PdCl2((3-Py)(2)SiMe2)](3). In a boiling chloroform solution, the cyclodimers are completely converted to the cyclotrimers. The structures of both cyclic species are locked at temperatures below 0 A degrees C. The cyclotrimer equilibrates to the cyclodimer, the cyclotrimer, and cyclotrimeric mono-DMF adduct, [Pd3Cl5(DMF)((3-Py)(2)SiMe2)(3)]Cl in the mole ratio of 6:1:5 in DMF solution at room temperature. The cyclodimer finally reaches the equilibrium in the same condition. English SPRINGER STRUCTURAL-PROPERTIES CYCLOTRIMER ASSEMBLIES CF3SO3 CARBON METAL PF6 Ring expansion and N,N-dimethylformamide-solvation of the cyclodimeric complex bis(3-pyridyl)dimethylsilanedicholoropalladium(II) Article 10.1007/s11243-009-9232-x 1 TRANSITION METAL CHEMISTRY, v.34, no.6, pp.579 - 584 TRANSITION METAL CHEMISTRY 34 6 579 584 scie scopus 000268906400001 2-s2.0-68849131736 Chemistry, Inorganic & Nuclear Chemistry Article STRUCTURAL-PROPERTIES CYCLOTRIMER ASSEMBLIES CF3SO3 CARBON METAL PF6