Lyubimov, Sergey E. Kalinin, Valery N. Tyutyunov, Andrey A. Olshevskaya, Valentina A. Dutikova, Yulia V. Cheong, Chan Seong Petrovskii, Pavel V. Safronov, Anton S. Davankov, Vadim A. 2024-01-20T22:04:22Z 2024-01-20T22:04:22Z 2021-09-01 2009-01 0899-0042 https://pubs.kist.re.kr/handle/201004/132859 A series of new fine-tunable monodentate phosphite and phosphoramidite ligands based on carboranes have been synthesized and used for asymmetric Rh-catalyzed hydrogenation of prochiral olefins with the result of up to 99.8% ee. Dependence of the enantio selectivity on the electron-withdrawing or electron-donating properties of the carboranyl substituent has been studied. Chirality 21:2-5, 2009. (C) 2008 Wiley-Liss, Inc. English WILEY PHOSPHORAMIDITE LIGANDS Chiral Phosphites Derived from Carboranes: Electronic Effect in Catalytic Asymmetric Hydrogenation Article 10.1002/chir.20565 1 CHIRALITY, v.21, no.1, pp.2 - 5 CHIRALITY 21 1 2 5 scie scopus 000261782900002 2-s2.0-60749137648 Chemistry, Medicinal Chemistry, Analytical Chemistry, Organic Pharmacology & Pharmacy Pharmacology & Pharmacy Chemistry Article PHOSPHORAMIDITE LIGANDS carboranes phosphites asymmetric hydrogenation electronic effect