Kim, Yong Joo Lee, Yoon Hee Lee, Mi Hyeon Kim, Hark Jin Pan, Jia Hong Lim, Goo Il Choi, Young S. Kim, Kyungkon Park, Nam-Gyu Lee, Chongmu Lee, Wan In 2024-01-20T22:30:38Z 2024-01-20T22:30:38Z 2021-08-31 2008-11-18 0743-7463 https://pubs.kist.re.kr/handle/201004/132975 Long-range ordered cubic mesoporous TiO2 films with 300 nm thickness were fabricated on fluorine-doped tin oxide (FTO) substrate by evaporation-induced self-assembly (EISA) process using F127 as a structure-directing agent. The prepared mesoporous TiO2 film (Meso-TiO2) was applied as an interfacial layer between the nanocrystalline TiO2 film (NC-TiO2) and the FTO electrode in the dye-sensitized solar cell (DSSC). The introduction of Meso-TiO2 increased J(sc) from 12.3 to 14.5 mA/cm(2), and V-oc by 55 mV, whereas there was no appreciable change in the fill factor (FF). As a result, the photovoltaic conversion efficiency (eta) was improved by 30.0% from 5.77% to 7.48%. Notably, introduction of Meso-TiO2 increased the transmittance of visible light through the FTO glass by 23% as a result of its excellent antireflective role. Thus the increased transmittance was a key factor in enhancing the photovoltaic conversion efficiency. In addition, the presence of interfacial Meso-TiO2 provided excellent adhesion between the FTO and main TiO2 layer, and suppressed the back-transport reaction by blocking direct contact between the electrolyte and FTO electrode. English AMER CHEMICAL SOC TITANIUM-DIOXIDE ELECTRON-TRANSPORT METAL-OXIDES LOW-COST RECOMBINATION PERFORMANCE CONVERSION COPOLYMER DIFFUSION TRIBLOCK Formation of Efficient Dye-Sensitized Solar Cells by Introducing an Interfacial Layer of Long-Range Ordered Mesoporous TiO2 Thin Film Article 10.1021/la802340g 1 LANGMUIR, v.24, no.22, pp.13225 - 13230 LANGMUIR 24 22 13225 13230 scie scopus 000260874800071 2-s2.0-57349105791 Chemistry, Multidisciplinary Chemistry, Physical Materials Science, Multidisciplinary Chemistry Materials Science Article TITANIUM-DIOXIDE ELECTRON-TRANSPORT METAL-OXIDES LOW-COST RECOMBINATION PERFORMANCE CONVERSION COPOLYMER DIFFUSION TRIBLOCK