Kim, Dae Hyun Kang, Jung Shik Lee, Yun Joo Park, Nam Kuk Kim, Young Chul Hong, Suk In Moon, Dong Ju 2024-01-20T23:02:00Z 2024-01-20T23:02:00Z 2021-09-03 2008-07-31 0920-5861 https://pubs.kist.re.kr/handle/201004/133308 Steam reforming of n-hexadecane, a main constituent of diesel, over noble metal-modified Ni-based hydrotalcite catalyst was carried out in a temperature range of 700-950 degrees C, at an atmospheric pressure with space velocity of 10,000-100,000 h(-1) and feed molar ratio of H2O/C = 3.0. The catalysts were prepared by a co-precipitation and dipping methods. The noble metal-modified Ni-based hydrotalcite catalyst displayed higher resistance for the sintering of active metal than the Ni-based hydrotalcite catalyst prepared by the conventional method. It was found that the Rh-modified Ni-based catalysts showed high resistance to the formation of carbon compared to Ni-based catalysts. The results suggest that Rh-modified Ni-based catalyst can be applied for the steam reforming (SR) reaction of diesel. (C) 2008 Elsevier B.V. All rights reserved. English ELSEVIER MG-AL HYDROTALCITE PHASE CRYSTALLIZATION METHOD PARTIAL OXIDATION LOADED CATALYST FUEL HYDROGEN METHANE CH4 GASOLINE RU Steam reforming of n-hexadecane over noble metal-modified Ni-based catalysts Article 10.1016/j.cattod.2008.01.021 1 CATALYSIS TODAY, v.136, no.3-4, pp.228 - 234 CATALYSIS TODAY 136 3-4 228 234 scie scopus 000257015200006 2-s2.0-44249124947 Chemistry, Applied Chemistry, Physical Engineering, Chemical Chemistry Engineering Article; Proceedings Paper MG-AL HYDROTALCITE PHASE CRYSTALLIZATION METHOD PARTIAL OXIDATION LOADED CATALYST FUEL HYDROGEN METHANE CH4 GASOLINE RU steam reforming n-hexadecane Ni-based catalyst noble metal-modified ni-based catalyst hydrotalcite carbon formation