Lee, Yongjae Lee, Hyun-Hwi Lee, Dong Ryeol Kim, Sun Jin Kao, Chi-chang 2024-01-20T23:32:38Z 2024-01-20T23:32:38Z 2021-09-03 2008-04 0022-4596 https://pubs.kist.re.kr/handle/201004/133606 The high-pressure compression behaviour of 3 different cation forms of gallosilicate zeolite with CGS topology has been investigated using in situ synchrotron X-ray powder diffraction and a diamond-anvil cell technique. Under hydrostatic conditions mediated by a nominally penetrating pressure-transmitting medium, unit-cell lengths and volume compression is modulated by different degrees of pressure-induced hydration and accompanying channel distortion. In a Na-exchanged CGS (Na10Ga10Si22O64 center dot 16H(2)O), the unit-cell volume expands by ca. 0.6% upon applying hydrostatic pressure to 0.2GPa, whereas, in an as-synthesized K-form (K10Ga10Si22O64 center dot 5H(2)O), this initial volume expansion is suppressed to ca. 0.1% at 0.16 GPa. In the early stage of hydrostatic compression below similar to 1 GPa, relative decrease in the ellipticity of the non-planar 10-rings is observed, which is then reverted to a gradual increase in the ellipticity at higher pressures above similar to 1 GPa, implying a change in the compression mechanism. In a Sr-exchanged sample (Sr5Ga10Si22O64 center dot 19H(2)O), on the other hand, no initial volume expansion is observed. Instead, a change in the slope of volume contraction is observed near 1.5 GPa, which leads to a 2-fold increase in the compressibility. This is interpreted as pressure-induced rearrangement of water molecules to facilitate further volume contraction at higher pressures. (C) 2008 Elsevier Inc. All rights reserved. English ACADEMIC PRESS INC ELSEVIER SCIENCE TSG-1 Cation-dependent anomalous compression of gallosilicate zeolites with CGS topology: A high-pressure synchrotron powder diffraction study Article 10.1016/j.jssc.2008.01.017 1 JOURNAL OF SOLID STATE CHEMISTRY, v.181, no.4, pp.730 - 734 JOURNAL OF SOLID STATE CHEMISTRY 181 4 730 734 scie scopus 000254962800007 2-s2.0-41249097666 Chemistry, Inorganic & Nuclear Chemistry, Physical Chemistry Article TSG-1 gallosilicate zeolites CGS synchrotron x-ray diffraction high-pressure anomalous volume contraction