Lee, Yongjae Kim, Sun Jin Kao, Chi-Chang Vogt, Thomas 2024-01-20T23:33:44Z 2024-01-20T23:33:44Z 2021-09-03 2008-03-05 0002-7863 https://pubs.kist.re.kr/handle/201004/133658 Two high-pressure phases of a potassium gallosilicate with a gismondine framework (K-GaSi-GIS) were characterized using Rietveld refinements of in-situ high-pressure, high-resolution synchrotron X-ray powder diffraction data. The observed response of the K-GaSi-GIS framework under hydrostatic pressure is a gradual flattening of the so-called "double crankshaft" structural chain units. At pressures below 1.0(1) GPa, additional water molecules from the hydrostatic pressure-transmitting medium are inserted into the potassium-water guest network ("pressure-induced hydration") resulting in a "super-hydrated" high-pressure phase I. As the flattening of the double crankshaft structural units in the GIS framework continues above 1.6 GPa, the ellipticity of the cross-linking 8-ring windows is reduced below a certain threshold, and a disordering of the potassium-water guest structure along the 8-ring channel, characteristic of a disordered high-pressure phase II, is observed. The concerted framework distortion and guest network disordering accommodates the increased hydration level while maintaining the seven-fold coordination environment of the potassium cations to framework oxygen atoms and water molecules. We have thus established the atomistic details of a guest-host order-disorder transition under pressure-induced hydration conditions in a zeolite with GIS framework and compared it to other zeolites during pressure-induced hydration. We find that the structural changes mediated by the extra-framework cations and their coordination environment under PIH conditions are at the core of these different mechanisms and are driving the changes in the ellipticity of pore openings, order-disorder and disorder-order transitions, and framework distortions. English AMER CHEMICAL SOC CRYSTAL-STRUCTURE STRUCTURAL EVOLUTION NEUTRON-DIFFRACTION RIETVELD REFINEMENT CATION MIGRATION NATROLITE EXCHANGE COMPRESSIBILITY BEHAVIOR WATER Pressure-induced hydration and order-disorder transition in a synthetic potassium gallosilicate zeolite with gismondine topology Article 10.1021/ja077443o 1 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.9, pp.2842 - 2850 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130 9 2842 2850 scie scopus 000253549800044 2-s2.0-40949083892 Chemistry, Multidisciplinary Chemistry Article CRYSTAL-STRUCTURE STRUCTURAL EVOLUTION NEUTRON-DIFFRACTION RIETVELD REFINEMENT CATION MIGRATION NATROLITE EXCHANGE COMPRESSIBILITY BEHAVIOR WATER Gallosilicate Zeolite Gismondine High-Pressure Synchrotron