Lee, Donghwan Cho, Sung Il Kim, Geon-Joong Kim, Honggon Lee, Ik-Mo 2024-01-21T00:04:13Z 2024-01-21T00:04:13Z 2021-09-02 2007-12 1226-086X https://pubs.kist.re.kr/handle/201004/133938 Efficient and selective catalytic systems, where Ni or Pd is introduced on the silicate material (ZSM-5) having micropore and mesopore structures, have been developed for the reduction of carboxylic acids with H-2 at room temperature. It is found that the catalytic activity depends on the hydrogen pressure, the agitation rate, the nature and the amount of active species. A plausible reaction mechanism for the hydrogenation of carboxylic acids to corresponding alcohols is proposed on the basis of electronic and steric effects in these reactions. English ELSEVIER SCIENCE INC MESOPOROUS MOLECULAR-SIEVE CARBON MESOSTRUCTURES REDUCTION PLATINUM SPHERES SILICA BONDS FILMS Efficient and selective hydrogenation of carboxylic acid catalyzed by Ni or Pd on ZSM-5 Article 1 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.13, no.7, pp.1067 - 1075 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 13 7 1067 1075 scie scopus kci ART001229357 000252451500004 Chemistry, Multidisciplinary Engineering, Chemical Chemistry Engineering Article MESOPOROUS MOLECULAR-SIEVE CARBON MESOSTRUCTURES REDUCTION PLATINUM SPHERES SILICA BONDS FILMS Ni Pd carboxylic acid alcohol ZSM-5 hydrogenation mechanism