Molander, Gary A. Ham, Jungyeob Seapy, Dave G. 2024-01-21T01:34:44Z 2024-01-21T01:34:44Z 2021-08-31 2007-01-15 0040-4020 https://pubs.kist.re.kr/handle/201004/134739 The Suzuki-Miyaura-type cross-coupling reaction of potassium alkyltrifluoroborates with various alkenyl bromides in the presence of 10 mol % of PdCl2(dppf)center dot CH2Cl2 and 3.0 equiv of Cs2CO3 in aqueous toluene at 80 degrees C provided the desired compounds in 63-95% yields. A variety of functional groups in the potassium alkyltrifluoroborates were tolerated under the basic conditions. (c) 2006 Elsevier Ltd. All rights reserved. English PERGAMON-ELSEVIER SCIENCE LTD EXPANDING ORGANOBORON CHEMISTRY EFFICIENT AGENTS ARYL DERIVATIVES CROTYLATION ALLYLATION ALDEHYDES CHLORIDES Palladium-catalyzed cross-coupling reaction of alkenyl bromides with potassium alkyltrifluoroborates Article 10.1016/j.tet.2006.10.088 1 TETRAHEDRON, v.63, no.3, pp.768 - 775 TETRAHEDRON 63 3 768 775 scie scopus 000243707700026 Chemistry, Organic Chemistry Article EXPANDING ORGANOBORON CHEMISTRY EFFICIENT AGENTS ARYL DERIVATIVES CROTYLATION ALLYLATION ALDEHYDES CHLORIDES Organotrifluoroborate Suzuki-Miyaura reaction alkenylbromides alkyltrifluoroborates cross-coupling reaction sp2-sp3 bond