Lee, T Song, KH Jung, I Kang, Y Lee, SH Kang, SO Ko, J 2024-01-21T03:06:03Z 2024-01-21T03:06:03Z 2021-09-01 2006-04-15 0022-328X https://pubs.kist.re.kr/handle/201004/135585 A novel series of blue emitting silylene-spaced diphenylanthracene derivatives have been synthesized and characterized. The rhodium-catalyzed hydrosilylation of bis[4-(dimethylsilyl)phenyl]anthracene 3-4 yielded stable 9,10-disubstituted (E)-divinylsilylenediphenylanthracene products 7-10 and salt elimination reaction of bis[4-(chlorodimethylsilyl)phenyllanthracene 5-6 gave 9,10-disubstituted disilyldiphenylanthracene compounds 11-14. They are fluorescent in the blue region with good quantum efficiencies. The rhodium-catalyzed polyaddition including 2-tert-butyl-9,10-bis[4-(dimethylsilyl)phenyl]anthracene (4) afforded the nonconjugated copolymer 15. (c) 2006 Elsevier B.V. All rights reserved. English ELSEVIER SCIENCE SA ENERGY-TRANSFER ELECTROLUMINESCENCE HYDROSILYLATION DIODES COMPLEXES POLYMERS ANTHRACENES MOLECULES EMISSION Silylene-spaced diphenylanthracene derivatives as blue-emitting materials Article 10.1016/j.jorganchem.2006.01.016 1 JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.691, no.9, pp.1887 - 1896 JOURNAL OF ORGANOMETALLIC CHEMISTRY 691 9 1887 1896 scie scopus 000236929300011 2-s2.0-33645392521 Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry Article ENERGY-TRANSFER ELECTROLUMINESCENCE HYDROSILYLATION DIODES COMPLEXES POLYMERS ANTHRACENES MOLECULES EMISSION electroluminescent silylene-spaced diphenylanthracene rhodium-catalyzed hydrosilylation