Kim, JS Yu, JK Lee, HS Kim, JY Kim, YC Han, JH Oh, IH Rhee, YW 2024-01-21T04:32:55Z 2024-01-21T04:32:55Z 2021-09-03 2005-09 0256-1115 https://pubs.kist.re.kr/handle/201004/136185 We investigated the effect of temperature, oxidant and catalyst loading on the performance of direct formic acid fuel cell (DFAFC). When oxidant was changed from air to oxygen, the power density was increased to 17.3 mW/ cm(2) at 25 degrees C. The power density of DFAFC operated with oxygen showed a maximum value of 40.04 mW/cm(2) with the temperature rise from room temperature to 70 degrees C. The highest power density of DFAFC using air was observed for Pt-Ru black catalyst with loading of 8 mgPt/cm(2) at room temperature. At 70 degrees C; however, the performance of catalyst with the loading of 4 mgPt/cm(2) was higher than that of 8 mgPt/cm(2). The DFAFC, operated with oxygen and catalyst of 4 mgPt/cm(2) loading, showed the best performance at all temperature range. The enhancement of cell performance with an increase of catalyst loading is believed to come from an increase of catalyst active sites. However, operated at higher temperature or with oxygen, the cell with higher catalyst loading showed lower performance than expected. It is speculated that the thick catalyst layer inhibits the proton transport. English KOREAN INSTITUTE CHEMICAL ENGINEERS CROSSOVER Effect of temperature, oxidant and catalyst loading on the performance of direct formic acid fuel cell Article 10.1007/BF02705779 1 KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.22, no.5, pp.661 - 665 KOREAN JOURNAL OF CHEMICAL ENGINEERING 22 5 661 665 scie scopus kci ART001118947 000232483600003 2-s2.0-29344461770 Chemistry, Multidisciplinary Engineering, Chemical Chemistry Engineering Article CROSSOVER fuel cell formic acid (HCOOH) anode catalyst DFAFC temperature