Kim, JH Kang, SH Jung, IN Kim, KM Yoo, BR Lee, ME 2024-01-21T06:13:36Z 2024-01-21T06:13:36Z 2021-09-05 2004-10 0928-0707 https://pubs.kist.re.kr/handle/201004/137191 Reaction of (triphenylmethyl)silanetriol (1) with cyclopentadienyltitanium trichloride (CpTiCl3) in the presence of triethylamine as a HCl scavenger gave both compounds of a partial open-cage type {[Ph3CSiO(OH)](3)(Ph3CSiO3/2)(CpTiO3/2)(4)} (2) and cube type (Ph3CSiO3/2CpTiO3/2)(4) (3). The 1:1 reaction of 1 and CpTiCl3 in toluene solvent at reflux temperature for 3 d afforded compounds 2 (22%) and 3 (36%). When 1 is reacted with a 1.5 fold excess of CpTiCl3 under the same conditions, compound 3 was obtained in high yield (81%) along with 2 in trace quantities. Compounds 2 and 3 were fully characterized by the analyses of H-1, C-13, Si-29 NMR, IR, and FAB MS data. The solid-state structure of 3 was determined by a single crystal X-ray diffraction study. Compound 3 had shown to have catalytic activity for the oxidation of alkenes such as 1-octene, cyclooctene, and norbornene with t-butyl hydrogen peroxide. The effect of solvent was observed in this epoxidation reaction. The order of reactivity were decreased as follows: CHCl3 > hexane >> THF. English SPRINGER CATALYSTS EPOXIDATION SILSESQUIOXANES Synthesis and structures of titanosiloxane cage compounds Article 10.1007/s10971-004-5760-1 1 JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, v.32, no.1-3, pp.31 - 35 JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY 32 1-3 31 35 scie scopus 000228103300005 2-s2.0-17744383794 Materials Science, Ceramics Materials Science Article; Proceedings Paper CATALYSTS EPOXIDATION SILSESQUIOXANES slanetriol cage compounds polytitanosiloxane polytitanosilsesquioxane cyclopentadienyltitanium trichloride alkene