Lee, H Kim, KH Kim, H Lee, SD Kim, HS 2024-01-21T07:40:31Z 2024-01-21T07:40:31Z 2021-09-02 2004-01-01 0022-1139 https://pubs.kist.re.kr/handle/201004/137947 The use of imidazolium-based ionic liquids as promoters was found to be highly effective for the hydrolysis reaction of CF3CH2Cl with aqueous potassium acetate to produce 2,2,2-trifluoroethanol (TFE). Among ionic liquids tested, 1-butyl-3-methylimidazolium chloride ([bmim]Cl) showed the highest yield of TFE, over 90%, which is almost two times higher than that obtained in the absence of an ionic liquid. The integrity of imidazolium salt was maintained during the reaction, which was confirmed from the recycling studies and H-1 NMR spectroscopy. (C) 2003 Elsevier B.V. All rights reserved. English ELSEVIER SCIENCE SA NUCLEOPHILIC DISPLACEMENT-REACTIONS LIQUID Imidazolium salt assisted hydrolysis of 1-chloro-2,2,2-trifluoroethane Article 10.1016/j.jfluchem.2003.10.014 1 JOURNAL OF FLUORINE CHEMISTRY, v.125, no.1, pp.95 - 97 JOURNAL OF FLUORINE CHEMISTRY 125 1 95 97 scie scopus 000188380000015 2-s2.0-0345761543 Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry Article NUCLEOPHILIC DISPLACEMENT-REACTIONS LIQUID 2,2,2-trifluoroethanol 1-chloro-2,2,2-trifluoroethane hydrolysis ionic liquid phase transfer catalyst