Kim, SS Lee, H Choi, JW Na, BK Song, HK 2024-01-21T08:02:38Z 2024-01-21T08:02:38Z 2021-09-03 2003-11-25 1226-086X https://pubs.kist.re.kr/handle/201004/138073 The effect of residence time on methane conversion, selectivities, and yields of products were studied in this work. Methane conversion was increased with the increase of the residence time. The maximum selectivities of ethane and propane were 29.5% and 14.0%, respectively, and they were the main products of methane conversion. Kinetics of the methane decomposition to C-2, C-3, and C-4 in a dielectric-barrier discharge was studied at atmospheric pressure, and the kinetic model of methane decomposition was proposed. The calculated values of the product distribution from kinetic model were found to be in agreement with the experimental data. From the proposed model, the reaction rate constant k(4) (C2H4 --> C3H8) was the highest. English KOREAN SOC INDUSTRIAL ENGINEERING CHEMISTRY HIGHER HYDROCARBONS CARBON-DIOXIDE CORONA DISCHARGE PARTIAL OXIDATION CONVERSION CATALYSTS PLASMAS REACTOR Kinetics of the methane decomposition in a dielectric-barrier discharge Article 1 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.9, no.6, pp.787 - 791 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 9 6 787 791 scie scopus kci other ART000902131 000187024200024 2-s2.0-17444376206 Chemistry, Multidisciplinary Engineering, Chemical Chemistry Engineering Article HIGHER HYDROCARBONS CARBON-DIOXIDE CORONA DISCHARGE PARTIAL OXIDATION CONVERSION CATALYSTS PLASMAS REACTOR methane plasma dielectric-barrier discharge hydrocarbons kinetics