Kim, JH Joo, SH Kim, CK Kang, YS Won, JK 2024-01-21T08:09:12Z 2024-01-21T08:09:12Z 2021-09-03 2003-10 1598-5032 https://pubs.kist.re.kr/handle/201004/138196 Silver salt complex membranes with glassy poly(methyl methacrylate) (PMMA) unexpectedly showed higher propylene permeance than those with rubbery poly(butyl methacrylate) (PBMA) where as neat PMMA is much less permeable to propylene than that of neat PBMA. Such unusual facilitated olefin transport has been systematically investigated by changing the side chain length of polymethacrylates (PMAs) from methyl, ethyl to butyl. The ab initio calculation showed almost the same electron densities of the carbonyl oxygens in the three PMAs, expecting very similar intensity of the interaction between carbonyl oxygen and silver ion. However, the interaction intensity decreases with the length of the alkyl side chain: PMMA > PEMA > PBMA according to wide angle X-ray scattering and FT-Raman spectroscopy. The difference in the interaction intensity may arise from the difference in the hydrophilicity of the three PMAs, as confirmed by the contact angle of water, which determines the concentrations of the ionic constituents of silver salts: free ion, contact ion pair and higher order ionic aggregate. However, propylene solubilities and facilitated propylene transport vary with the side chain length significantly even at the same concentration of the free ion, the most active olefin carrier, suggesting possible difference in the prohibition of the molecular access of propylene to silver ion by the side chains: the steric hindrance. Therefore, it may be concluded that both the hydrophilicity and the steric hindrance associated with the side chain length in the three PMAs are of pivotal importance in determining facilitated olefin transport through polymer/silver salt complex membranes. English SPRINGER SILVER-POLYMER ELECTROLYTES X-RAY-SCATTERING POLY(PROPYLENE OXIDE) POLY(ETHYLENE OXIDE) MOLECULAR-WEIGHT IONS MEMBRANES DENSITY COORDINATION BEHAVIOR Unusual facilitated olefin transport through polymethacrylate/silver salt complexes Article 10.1007/BF03218379 1 MACROMOLECULAR RESEARCH, v.11, no.5, pp.375 - 381 MACROMOLECULAR RESEARCH 11 5 375 381 scie scopus kci ART001190006 000220056400013 2-s2.0-0242606847 Polymer Science Polymer Science Article SILVER-POLYMER ELECTROLYTES X-RAY-SCATTERING POLY(PROPYLENE OXIDE) POLY(ETHYLENE OXIDE) MOLECULAR-WEIGHT IONS MEMBRANES DENSITY COORDINATION BEHAVIOR silver ion facilitated transport olefin side chain polymethacrylat