Lee, YA Yoo, KH Jung, OS 2024-01-21T09:12:00Z 2024-01-21T09:12:00Z 2022-01-10 2003-03 1387-7003 https://pubs.kist.re.kr/handle/201004/138780 The reaction of cis, cis-[Pt-II(9-fm)(dmpda)] (9-fm = 9-fluorenylidenemalonate, dmpda = 2,2-dimethyl-1,3-propanediamine) with hydrogen peroxide in ethyleneglycol produces cis, trans, cis-[Pt-IV (9-fm)(OCH2CH2OH)(OH)(dmpda)]. Its crystal structure shows that the local geometry around the platinum atom approximates a typical octahedral arrangement with the added OCH2CH2OH/OH ligands in trans coordination sites. The molecules are packed in a two-dimensional assembly via van der Waals interactions, where the hydrophobic fluorenyl groups are arranged on both faces of the assembly plate whereas the hydrophilic groups fill up the inner part of the plate. The compound bearing both "inorganic OH" and "organic OH'' is a potential precursor for further various functionalizations. (C) 2002 Elsevier Science B.V. All rights reserved. English ELSEVIER SCIENCE BV PLATINUM(II) COORDINATION LIGANDS BONDS Oxidation of Pt(II) to Pt(IV) complex with hydrogen peroxide in glycols Article 10.1016/S1387-7003(02)00752-9 1 INORGANIC CHEMISTRY COMMUNICATIONS, v.6, no.3, pp.249 - 251 INORGANIC CHEMISTRY COMMUNICATIONS 6 3 249 251 scie scopus 000180981500007 2-s2.0-0037368451 Chemistry, Inorganic & Nuclear Chemistry Article PLATINUM(II) COORDINATION LIGANDS BONDS platinum(IV) complex oxidation ethyleneglycoloxylation 9-fluorenylidenemalonate