Lee, SJ Jun, JH Lee, SH Yoon, KJ Lim, TH Nam, SW Hong, SA 2024-01-21T10:41:45Z 2024-01-21T10:41:45Z 2021-09-05 2002-04-30 0926-860X https://pubs.kist.re.kr/handle/201004/139591 It was found that nickel-added strontium phosphate exhibited high activity and selectivity in partial oxidation of methane. The optimum nickel content could be determined. Over the optimum catalyst, methane conversions and H-2 and CO concentrations in excess of those predicted by the thermodynamic equilibrium were observed. It is believed that the catalytically active species is metallic nickel. This metallic nickel is considered to come from nickel-substituted strontium phosphate under reducing C environment, giving highly dispersed nickel metal particles. (C) 2002 Elsevier Science B.V. All rights reserved. English ELSEVIER SCIENCE BV SYNTHESIS GAS CATALYST SYNGAS H-2 CO CONVERSION NI/AL2O3 NI/YB2O3 Partial oxidation of methane over nickel-added strontium phosphate Article 10.1016/S0926-860X(01)00995-4 1 APPLIED CATALYSIS A-GENERAL, v.230, no.1-2, pp.61 - 71 APPLIED CATALYSIS A-GENERAL 230 1-2 61 71 scie scopus 000175431500007 2-s2.0-0037197630 Chemistry, Physical Environmental Sciences Chemistry Environmental Sciences & Ecology Article SYNTHESIS GAS CATALYST SYNGAS H-2 CO CONVERSION NI/AL2O3 NI/YB2O3 nickel partial oxidation of methane strontium phosphate syngas