Ahn, DR Kim, TW Hong, JI 2024-01-21T12:05:54Z 2024-01-21T12:05:54Z 2021-09-01 2001-07-27 0022-3263 https://pubs.kist.re.kr/handle/201004/140306 A group of iron(II) tris-bipyridine complexes bearing L-amino acids (L-Lys, L-Phe, L-Ser, L-Val) was prepared to investigate the predetermination of chirality of metal complexes by the chiral amino acid subunits. Noncovalent interactions and solvent polarity seemed to be important factors in inducing diastereoselectivity of the metal complexes. These phenomena were explained by H-1 NMR and CD spectroscopic studies and molecular mechanics calculations. English AMER CHEMICAL SOC METAL-COMPLEXES STEREOSELECTIVE SYNTHESIS MOLECULES Induction of diastereoselectivity in Fe(II) tris(amino acid-bipyridine) complexes Article 10.1021/jo001261u 1 JOURNAL OF ORGANIC CHEMISTRY, v.66, no.15, pp.5008 - 5011 JOURNAL OF ORGANIC CHEMISTRY 66 15 5008 5011 scie scopus 000170119600005 Chemistry, Organic Chemistry Article METAL-COMPLEXES STEREOSELECTIVE SYNTHESIS MOLECULES bipyridine diastereoselectivity amino acid iron complex