Jeong, HK Kim, SC Han, C Lee, H Song, HK Na, BK 2024-01-21T12:42:25Z 2024-01-21T12:42:25Z 2021-09-04 2001-03 0256-1115 https://pubs.kist.re.kr/handle/201004/140696 Conversion of methane to C-2/C-3 or higher hydrocarbons in a pulsed DC barrier discharge at atmospheric pressure was studied. Non-equilibrium plasma was generated in the barrier discharge reactor. In this plasma, electrons which had sufficient energy collided with the molecules of methane, which were then activated and coupled to C-2/C-3 or higher hydrocarbons. The effect of the change of applied voltage, pulse frequency and methane flow rate on methane conversion, selectivities and yields of products was studied. Methane conversion to higher hydrocarbons was about 25% as the maximum. Ethane, propane and ethylene were produced as primary products, including a small amount of unidentified C-4 hydrocarbons. The selectivity and yield of ethane as a main product cane to about 80% and 17% as the highest, respectively. The selectivities of ethane and ethylene were influenced not by the change of pulse frequency but by the change of applied voltage and methane flow rate. However, in case of propane, the selectivity was independent of those condition changes. The effect of the packing materials such as glass and Al2O3 bead on methane conversion was also considered, showing that Al2O3, played a role in enhancing the selectivity of ethane remarkably as a catalyst. English KOREAN INST CHEM ENGINEERS CORONA DISCHARGE OXIDATIVE DIMERIZATION NATURAL-GAS OXIDE DECOMPOSITION PLASMA Conversion of methane to higher hydrocarbons in pulsed DC barrier discharge at atmospheric pressure Article 10.1007/BF02698459 1 KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.18, no.2, pp.196 - 201 KOREAN JOURNAL OF CHEMICAL ENGINEERING 18 2 196 201 scie scopus kci other 000168021400009 2-s2.0-0000884560 Chemistry, Multidisciplinary Engineering, Chemical Chemistry Engineering Article CORONA DISCHARGE OXIDATIVE DIMERIZATION NATURAL-GAS OXIDE DECOMPOSITION PLASMA CH4 plasma barrier discharge methane conversion natural gas