Kim, BC Hwang, SS Lim, KY Yoon, KY 2024-01-21T13:10:08Z 2024-01-21T13:10:08Z 2021-09-05 2000-11-07 0021-8995 https://pubs.kist.re.kr/handle/201004/140925 To improve the mechanical properties of blends of polypropylene (PP) and terpolymer of ethylene-propylene-diene, (EPDM), a triblock copolymer, (PP-g-MAH)-co-[PA-6,6]-co-(EPDM-g-MAH), was synthesized by coupling reaction of maleic anhydride (MAH)-grafted PP (PP-g-MAH), EPDM-g-MAH, and PA-6,6. The newly prepared block copolymer brought about a physical interlocking between the blend components, and imparted a compatibilizing effect to the blends. Introducing the block copolymer to the blends up to 5 wt % lead to formation of a beta-form crystal. The wide-angle X-ray diffractograms measured in the region of 2 theta between 10 degrees and 50 degrees ascertained that incorporating the block copolymer gave a new peak at 2 theta = 15.8 degrees. The new peak was assigned to the (300) plane spacings of the beta-hexagonal crystal structure. In addition, the block copolymer notably improved the low-temperature impact property of the PP/EPDM blends. The optimum usage level of the compatibilizer proved to be 0.5 wt %. (C) 2000 John Wiley & Sons, Inc. English JOHN WILEY & SONS INC POLYPROPYLENE RUBBER MORPHOLOGY POLYAMIDE-6 Toughening of PP/EPDM blend by compatibilization Article 10.1002/1097-4628(20001107)78:6<1267::AID-APP130>3.0.CO;2-B 1 JOURNAL OF APPLIED POLYMER SCIENCE, v.78, no.6, pp.1267 - 1274 JOURNAL OF APPLIED POLYMER SCIENCE 78 6 1267 1274 scie scopus 000089337900013 2-s2.0-0034619288 Polymer Science Polymer Science Article POLYPROPYLENE RUBBER MORPHOLOGY POLYAMIDE-6 polypropylene/EPDM blend polyamide-6,6-based compatibilizer impact properties physical interlocking