Baek, NS Song, YB Kim, HK Hwang, SS Hong, SM 2024-01-21T13:36:33Z 2024-01-21T13:36:33Z 2021-09-05 2000-09 1058-725X https://pubs.kist.re.kr/handle/201004/141138 Polyimides containing hydroxyl group, so-called poly(hydroxy-imide)s, were prepared by the thermal imidization in the presence of m-cresol. The poly(hydroxy-imide)s exhibited high resistance to thermal degradation, with 10% weight loss temperature starring at near 527 degreesC in air. The organic/inorganic hybrid materials were prepared with TEOS by acid-catalyzed sol-gel reaction of sol-gel polyimide precursors obtained from die coupling reaction of the poly(hydroxy-imide) with 3-(triethoxysilyl)propyl isocyanate. All of the cured hybrid films spin-coated on ITO glass are transparent. The initial decomposition temperature was recorded at 356 degreesC. The dielectric constant of a hybrid material Rim was 3.24 at the frequency of 10kHz. The hybrid materials retained the coefficient of thermal expansion up to 3 pDm/degreesC below Tg and 30 ppm/degreesC above Tg. English GORDON BREACH SCI PUBL LTD Preparation and characterization of organic-inorganic hybrid materials via sol-gel reaction for interlayer dielectrics Article 10.1080/10587250008024915 1 MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.349, pp.263 - 266 MOLECULAR CRYSTALS AND LIQUID CRYSTALS 349 263 266 N scie scopus 000165236400066 2-s2.0-0034480249 Chemistry, Multidisciplinary Crystallography Materials Science, Multidisciplinary Chemistry Crystallography Materials Science Article; Proceedings Paper poly(hydroxy-imide) interlayer dielectrics organic/inorganic hybrid materials thermal expansion coefficient