Quirk, RP Yoo, T Lee, Y Kim, J Lee, B 2024-01-21T13:40:34Z 2024-01-21T13:40:34Z 2021-09-05 2000-08 0065-3195 https://pubs.kist.re.kr/handle/201004/141208 The use of 1,1-diphenylethylenes in anionic polymerization is reviewed. The structure and reactivity of 1,1-diphenylethylenes and the corresponding simple and polymeric 1,1-diphenylalkyllithiums are described. The applications of 1,1-diphenylethylene chemistry include: 1. Their use to form initiators 2. End-capping agents to attenuate reactivity for crossover to reactive, polar monomers or for functionalization reactions 3. For chain-end and in-chain functionalization using substituted 1,1-diphenylethylenes and 1,1-diarylethylenes 4. The preparation and applications of non-homopolymerizable 1,1-diphenylethylene-functionalized macromonomers 5. The use of bis(1,1-diphenylethylenes) and tris(1,1-diphenylethylenes) as precursors for hydrocarbon-soluble dilithium and trilithium initiators, respectively 6. The use of bis(1,1-diphenylethylenes) and tris(1,1-diphenylethylenes) as living linking agents to prepare heteroarm (miktoarm) star-branched polymers. English SPRINGER-VERLAG BERLIN CHAIN-END FUNCTIONALIZATION METHACRYLATE) DIBLOCK COPOLYMERS TRIARM STAR COPOLYMER LITHIUM TERT-BUTOXIDE LIVING POLYMERIZATION BLOCK-COPOLYMERS DILITHIUM INITIATORS METHYL-METHACRYLATE ORGANOLITHIUM COMPOUNDS ENERGY-TRANSFER Applications of 1,1-diphenylethylene chemistry in anionic synthesis of polymers with controlled structures Article 1 BIOPOLYMERS/PVA HYDROGELS/ANIONIC POLYMERISATION NANOCOMPOSITES, v.153, pp.67 - 162 BIOPOLYMERS/PVA HYDROGELS/ANIONIC POLYMERISATION NANOCOMPOSITES 153 67 162 scie scopus 000165688300003 2-s2.0-0034447412 Polymer Science Polymer Science Review CHAIN-END FUNCTIONALIZATION METHACRYLATE) DIBLOCK COPOLYMERS TRIARM STAR COPOLYMER LITHIUM TERT-BUTOXIDE LIVING POLYMERIZATION BLOCK-COPOLYMERS DILITHIUM INITIATORS METHYL-METHACRYLATE ORGANOLITHIUM COMPOUNDS ENERGY-TRANSFER anionic polymerization living anionic polymerization 1,1-diphenylalkyllithiums functionalized polymers block copolymers macromonomers star-branched polymers dilithium initiators trilithium initiators multifunctional initiators living linking reactions heteroarm star polymers miktoarm star polymers