Kim, JY Hong, SU Won, J Kang, YS 2024-01-21T14:08:32Z 2024-01-21T14:08:32Z 2021-09-05 2000-04-18 0024-9297 https://pubs.kist.re.kr/handle/201004/141445 Three explicit mathematical models have been developed to predict glass transition temperatures of binary polymery-diluent and polymer-salt systems as well as ternary polymer-diluent-salt systems based on the configurational entropy model and the Flory-Huggins theory. In the presence of salt, the specific ionic interactions of polymer and/or diluent with salts have been taken into account. The validity of the mathematical models mere examined against the experimental glass transition temperatures of poly(2-ethyl-2-oxazoline)-propylene carbonate, poly(2-ethyl-2-oxazoline)-silver triflate, and poly(propylene oxide)-lithium iodide as well as poly(2-ethyl-2-oxazoline)-propylene carbonate -silver triflate. The models adequately predict glass transition temperatures depending on the concentrations of the diluent as well as the salt in both binary and ternary systems. English AMER CHEMICAL SOC STATISTICAL THERMODYNAMICS ELECTROLYTES BEHAVIOR Molecular model and analysis of glass transition temperatures for polymer-diluent-salt systems Article 10.1021/ma991792o 1 MACROMOLECULES, v.33, no.8, pp.3161 - 3165 MACROMOLECULES 33 8 3161 3165 scie scopus 000086676700055 2-s2.0-0033750730 Polymer Science Polymer Science Article STATISTICAL THERMODYNAMICS ELECTROLYTES BEHAVIOR