Baek, HS 유병우 Keum, SR Yoon, CM Kim, SH Kim, JH 2024-01-21T14:37:00Z 2024-01-21T14:37:00Z 2021-09-05 2000-01 0039-7911 https://pubs.kist.re.kr/handle/201004/141693 alpha-Haloketones reacted with acyl cyanides to form 1,3-diketones in the presence of samarium diiodide. The reaction was assumed to proceed:via a mechanism involving samarium enolates formed in situ from alpha -haloketones. English MARCEL DEKKER INC Synthesis of 1,3-diketones by reaction of alpha-haloketones with acyl cyanides promoted by samarium diiodide Article 10.1080/00397910008087289 1 SYNTHETIC COMMUNICATIONS, v.30, no.1, pp.31 - 38 SYNTHETIC COMMUNICATIONS 30 1 31 38 N scie scopus 000085358900005 2-s2.0-0033953906 Chemistry, Organic Chemistry Article ALDOL-TYPE REACTION ORGANIC-SYNTHESIS FACILE SYNTHESIS ACID-CHLORIDES HALO KETONES TRIIODIDE IODIDE ROUTE SMI2 samarium diiodie 1,3-diketone α-haloketone acylcyanide