Ahn, KD Kim, JM Lee, CW Han, D Lee, DY Lee, YM 2024-01-21T14:38:24Z 2024-01-21T14:38:24Z 2021-09-04 2000-01 1060-1325 https://pubs.kist.re.kr/handle/201004/141718 Three bifunctional N-phenylmaleimide derivatives, N-[4-(2-hydroxy-3-methacryloyloxy propyloxycarbonyl)phenyl]maleimide (GMAPMI, 1), N-(4-methacryloyloxyphenyl) maleimide (MAPMI, 2) and 4-(4-maleimidobenzoyloxy)styrene (MIBOSt, 3) having radically polymerizable maleimide and vinyl groups together have been synthesized and polymerized. Polymerizations of the bifunctional maleimide monomers were carried out using a radical initiator at 55 degrees C and the results were compared with those obtained by self-polymerization in the absence of initors. All of the polymers obtained were insoluble in organic solvents owing to cross-linking between different functional groups. The reactivity for homopolymerization of monomer 3 is higher than that of monomers 1 and 2 because the styryl moiety of monomer 3 has better electron-donor strength than the methacrylate moiety. Under the same conditions, GMAPMI was copolymerized with N-vinyl-2-pyrrolidone and styrene as an electron-donor to give higher conversions by electron-donor/acceptor polymerization in which the maleimide moiety of GMAPMI mainly involved as an electron acceptor. English MARCEL DEKKER INC CHARGE-TRANSFER POLYMERIZATIONS N-PHENYLMALEIMIDE MALEIC-ANHYDRIDE DIELS-ALDER COPOLYMERIZATION POLYMERS COMPLEX STYRENE POLYMALEIMIDES MONOMERS Synthesis and radical polymerization of bifunctional maleimides with different functional reactivities Article 10.1081/MA-100101084 1 JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, v.37, no.1-2, pp.117 - 131 JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY 37 1-2 117 131 scie scopus 000085337600008 2-s2.0-0008756996 Polymer Science Polymer Science Article CHARGE-TRANSFER POLYMERIZATIONS N-PHENYLMALEIMIDE MALEIC-ANHYDRIDE DIELS-ALDER COPOLYMERIZATION POLYMERS COMPLEX STYRENE POLYMALEIMIDES MONOMERS bifunctional maleimide derivatives phenylmaleimides with methacryloyl or styryl group electron-donor/acceptor polymerization