Jo, SM Lee, WS Oh, HJ Park, S Ahn, BS Park, KY 2024-01-21T15:01:50Z 2024-01-21T15:01:50Z 2021-09-04 1999-11 0379-153X https://pubs.kist.re.kr/handle/201004/141876 Poly(vinylidene fluoride)s(PVDFs), which were polymerized by di-t-butyl peroxide (DTBP), an initiator, at high temperature, showed low melting temperature, low crystallinity, and high contents of head-to-head inversion. The main crystal structure was cr-form (Phase II) and it showed good thermochemical stability due to their nonpolar end group. PVDF by ammonium peroxodisulfate (APS) showed higher melting temperature, higher crystallinity, and lower contents of head-to-head inversion than those by DTBP. The main crystal structures were beta-form (Phase I), but the content of alpha-form increased at high polymerization temperature. It also showed poor thermochemical stability because of their polar end group and low contents of head-to-head inversion. Korean POLYMER SOC KOREA POLY(VINYLIDENE FLUORIDE) A study on polymerization of PVDF based fluoropolymers with high performance for battery (I) Article 1 POLYMER-KOREA, v.23, no.6, pp.800 - 808 POLYMER-KOREA 23 6 800 808 scie scopus 000084050300004 2-s2.0-17444407718 Polymer Science Polymer Science Article POLY(VINYLIDENE FLUORIDE) poly(vinylidene fluoride) DTBP APS end group thermochemical stability