Lee, SG Lim, CW Song, CE Kim, IO 2024-01-21T17:42:48Z 2024-01-21T17:42:48Z 2021-09-05 1997-12-23 0957-4166 https://pubs.kist.re.kr/handle/201004/143450 C-2-Symmetric (4S,4'S)-2,2'-bis(o-diphenylphosphinophenyl)-4,4',5,5'- tetrahydro-4,4'-bi(1,3-oxazole) (1, Phos-Bidx) has been designed and synthesized as a chiral ligand for metal-catalyzed reactions. The Phos-Biox 1 was found to be an efficient ligand for rhodium(I)-catalyzed asymmetric reduction of prochiral acetophenones with diphenylsilane to give optically active secondary alcohols of up to 97% ee. (C) 1997 Elsevier Science Ltd. All rights reserved. English PERGAMON-ELSEVIER SCIENCE LTD CATALYZED ASYMMETRIC HYDROSILYLATION CONTAINING OXAZOLINE LIGANDS PHOSPHINE HYBRID LIGAND ALLYLIC SUBSTITUTION CYCLOPROPANATION COMPLEXES HYDROGENATION OLEFINS DERIVATIVES ALKYLATIONS A new C-3-symmetric chiral bisphosphine ligand containing a bioxazole backbone: highly enantioselective hydrosilylation of ketones Article 10.1016/S0957-4166(97)00554-5 1 TETRAHEDRON-ASYMMETRY, v.8, no.24, pp.4027 - 4031 TETRAHEDRON-ASYMMETRY 8 24 4027 4031 scie scopus 000071304500010 2-s2.0-0031584574 Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical Chemistry Article CATALYZED ASYMMETRIC HYDROSILYLATION CONTAINING OXAZOLINE LIGANDS PHOSPHINE HYBRID LIGAND ALLYLIC SUBSTITUTION CYCLOPROPANATION COMPLEXES HYDROGENATION OLEFINS DERIVATIVES ALKYLATIONS C//2-symmetric bioxazole ligand