Kim, BK Hamaguchi, HO 2024-01-21T18:04:00Z 2024-01-21T18:04:00Z 2021-09-04 1997-10 0370-1972 https://pubs.kist.re.kr/handle/201004/143584 The mode assignments of the sixteen Raman bands observed for monoclinic zirconia (ZrO2) have been made by measuring the Raman spectra of the cationic-as well as the anionic-labelled com pounds, that is, Zr-91.22((O1-xOx)-O-16-O-18)(2) (x = 0.002 to 0.760) and (ZrO2)-Zr-93.80-O-16. The four Raman bands at 334, 224, 192, and 180 cm(-1) were not influenced by the O-16-O-18 substitution but were shifted to lower wavenumbers by the Zr-91.22-Zr-93.80 substitution, from which they are assigned to the Zr-Zr vibrations. The three Raman bands at 380. 349. and 308 cm(-1) were shifted to lower wavenumbers by the Zr-91.22-Zr-93.80 as well as the O-16-O-18 substitution, from which they are assigned to the Zr-O vibrations. The eight Raman bands at 800 to 382 cm(-1) and the band at 105 cm(-1) were shifted to lower wavenumbers by the O-16-O-18 substitution but were shifted to higher wavenumbers by the Zr-91.22-(93.80)Z, substitution, from which they are assigned to the O-O vibrations. English AKADEMIE VERLAG GMBH SELF-DIFFUSION COEFFICIENTS TEMPERATURE-DEPENDENCE HAFNIA OXYGEN Mode assignments of the Raman spectrum of monoclinic zirconia by isotopic exchange technique Article 10.1002/1521-3951(199710)203:2<557::AID-PSSB557>3.0.CO;2-C 1 PHYSICA STATUS SOLIDI B-BASIC RESEARCH, v.203, no.2, pp.557 - 563 PHYSICA STATUS SOLIDI B-BASIC RESEARCH 203 2 557 563 scie scopus A1997YD05600030 2-s2.0-0031508339 Physics, Condensed Matter Physics Article SELF-DIFFUSION COEFFICIENTS TEMPERATURE-DEPENDENCE HAFNIA OXYGEN mode assignment