SONG, CE ROH, EJ LEE, SG KIM, IO 2024-01-21T20:31:58Z 2024-01-21T20:31:58Z 2022-01-10 1995-11 0957-4166 https://pubs.kist.re.kr/handle/201004/144935 Heterogeneous catalytic asymmetric dihydroxylation of olefins using homo- and co-polymeric cinchona alkaloids has been reported. The benzoate type homopolymers 2a, b showed high enantioselectivity in the heterogeneous ADH reactions, but their catalytic efficiency was largely dependent on the solvent system which may relate to the accessibility of the active catalytic site. The influence of polymer backbone polarity on the compatibility with the reaction medium was investigated using copolymers 3a, b and 4 having polar polymer backbone. The reaction rates and optical yields were dramatically increased by increasing the polarity of the polymer backbone in NMO-acetone/H2O system. English PERGAMON-ELSEVIER SCIENCE LTD R-AMINO-ACIDS ORGANIC SYNTHESES HYDRATROPIC ACID ALKENES HYDROGENATION LIGANDS SCOPE POLYMERIC CINCHONA ALKALOIDS FOR THE HETEROGENEOUS CATALYTIC ASYMMETRIC DIHYDROXYLATION OF OLEFINS - THE INFLUENCE OF THE POLYMER BACKBONE POLARITY ON THE COMPATIBILITY BETWEEN POLYMER SUPPORT AND REACTION MEDIUM Article 10.1016/0957-4166(95)00358-V 1 TETRAHEDRON-ASYMMETRY, v.6, no.11, pp.2687 - 2694 TETRAHEDRON-ASYMMETRY 6 11 2687 2694 scie scopus A1995TG43100017 2-s2.0-0028880555 Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical Chemistry Article R-AMINO-ACIDS ORGANIC SYNTHESES HYDRATROPIC ACID ALKENES HYDROGENATION LIGANDS SCOPE stereochemistry