WOO, HG KIM, SY CHO, EJ JUNG, IN 2024-01-21T20:45:53Z 2024-01-21T20:45:53Z 2022-01-10 1995-02-20 0253-2964 https://pubs.kist.re.kr/handle/201004/145168 Substituted 3-phenyl-1-silabutanes, 3-chlorophenyl-1-silabutane (1), 3-tolyl-1-silabutane (2), and 3-phenoxyphenyl-1-silabutane (3), were prepared in 68-98% yield by reduction of the corresponding substituted 3-phenyl-1,1-dichloro-1-silabutanes with LiAlH4. The dehydrogenative homopolymerization and copolymerization of the silanes were performed with Cp(2)MCl(2)/Red-Al (M=Ti, Hf) catalyst system. The molecular weights of the resulting polymers were in the range of 600 to 1100 (vs polystyrene) with degree of polymerization (DP) of 5 to 8 and polydispersity index (PDI) of 1.6 to 3.8. The monomer silanes underwent the dehydrogenative polymerization with Cp(2)TiCl(2)/Red-Al catalyst to produce somewhat higher molecular weight polysilanes compared with Cp(2)HfCl(2)/Red-Al catalyst. English KOREAN CHEMICAL SOC BOND METATHESIS MECHANISM POLYSILANE HIGH POLYMERS PRIMARY ORGANOSILANES COMPLEXES SILANES DEHYDROPOLYMERIZATION PHENYLSILANE ZIRCONOCENE DEHYDROGENATIVE POLYMERIZATION OF NEW ALKYLSILANES CATALYZED BY CP(2)MCL(2)/RED-AL SYSTEM (M=TI, HF) Article 1 BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.16, no.2, pp.138 - 143 BULLETIN OF THE KOREAN CHEMICAL SOCIETY 16 2 138 143 scie A1995QK51300016 Chemistry, Multidisciplinary Chemistry Article BOND METATHESIS MECHANISM POLYSILANE HIGH POLYMERS PRIMARY ORGANOSILANES COMPLEXES SILANES DEHYDROPOLYMERIZATION PHENYLSILANE ZIRCONOCENE dehydrogenative polymerization