JUNG, IN YEON, SH HAN, JS 2024-01-21T22:32:16Z 2024-01-21T22:32:16Z 2021-09-02 1993-06 0276-7333 https://pubs.kist.re.kr/handle/201004/146040 A series of Si-H-containing bis(silyl)methanes has been prepared by reacting directly elemental silicon simultaneously with (chloromethyl)silanes and hydrogen chloride in the presence of a coppercatalyst using a stirred reactor equipped with a spiral band agitator at carefully controlled temperatures between 280 and 340-degrees-C. Bis(silyl)methanes containing dichlorosilyl groups were obtained as the major products and trichlorosilyl-group-containing bis(silyl)methanes as minor products. Cadmium was a good promoter for the reaction, while zinc was found to be an inhibitor. English AMER CHEMICAL SOC DIRECT SYNTHESIS OF BIS(SILYL)METHANES CONTAINING SI-H BONDS Article 10.1021/om00030a052 1 ORGANOMETALLICS, v.12, no.6, pp.2360 - 2362 ORGANOMETALLICS 12 6 2360 2362 scie scopus A1993LG15800052 2-s2.0-0000397197 Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry Note organosilane direct synthesis bis(silyl)methane