YOO, BR JUNG, IN LEE, ME KIM, CH 2024-01-21T23:40:11Z 2024-01-21T23:40:11Z 2021-09-02 1991-10-20 0253-2964 https://pubs.kist.re.kr/handle/201004/146725 The reaction of dichlorophenylvinylsilane with tert-butyllithium in hydrocarbon solvents at room temperature or below generated the Z and E-isomers of 1-chloro-1-phenyl-2-neopentylsilene. The intermediates were trapped by cyclopentadiene, anthracene and methoxytrimethylsilane to give a consistent 90/10 ratio for the Z-silene to E-silene adduct. This result was interpreted as an evidence for stereochemical induction in the silene generation reaction. English KOREAN CHEMICAL SOC SILENE STEREOCHEMISTRY ALPHA-LITHIOSILANES "1-METHYL-1-PHENYL-2-NEOPENTYLSILENE STEREOCHEMICAL INDUCTION IN THE GENERATION OF 1-CHLORO-1-PHENYL-2-NEOPENTYLSILENE Article 1 BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.12, no.5, pp.517 - 520 BULLETIN OF THE KOREAN CHEMICAL SOCIETY 12 5 517 520 scie A1991GP60400018 Chemistry, Multidisciplinary Chemistry Article SILENE STEREOCHEMISTRY ALPHA-LITHIOSILANES "1-METHYL-1-PHENYL-2-NEOPENTYLSILENE stereochemical induction generation 1-chloro-1-phenyl-2-neopentylsilene