JUNG, IN LEE, GH YEON, SH SUK, MY 2024-01-21T23:41:59Z 2024-01-21T23:41:59Z 2022-01-10 1991-08-20 0253-2964 https://pubs.kist.re.kr/handle/201004/146754 A series of trisilaalkanes has been prepared in high yields by the direct reaction of alpha-chloromethylsilanes with metallic silicon in the presence of copper catalyst using the stirred reactor equipped with a spiral band agitator at the carefully controlled temperature between 280-degrees-C and 340-degrees-C. Disilaalkane compounds were obtained as the minor products. Cadmium was found to be a good promotor for the reactions, while zinc was an inhibitor. English KOREAN CHEMICAL SOC DIRECT SYNTHESIS OF TRISILAALKANES Article 1 BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.12, no.4, pp.445 - 449 BULLETIN OF THE KOREAN CHEMICAL SOCIETY 12 4 445 449 scie A1991GC68800026 Chemistry, Multidisciplinary Chemistry Article direct synthesis trisilaalkanes silicon