최예지 김성준 김창혁 이선엽 임형진 안예진 하현주 최유리 김진영 최성득 이승복 2024-02-22T08:00:10Z 2024-02-22T08:00:10Z 2024-02-22 2024-02 1598-7132 https://pubs.kist.re.kr/handle/201004/149306 Hazardous air pollutants (HAPs) are primarily emitted from human activities in industrial and urban areas, and they have adverse impacts on human health. While many studies have focused on monitoring individual HAPs in Seoul, simultaneous measurements of various types of HAPs have been rare. In this study, therefore, volatile organic compounds (VOCs), carbonyl compounds, particle-bound polycyclic aromatic hydrocarbons (pPAHs), black carbon (BC), heavy metals, and criteria air pollutants (CAPs) were simultaneously measured at a site in Yangcheon-gu, Seoul, Korea. The concentrations of most VOCs were high in the fall and spring mainly due to low wind speeds. Conversely, several VOCs emitted from solvents in industrial and urban areas exhibited high concentrations in the summer. Benzene was positively correlated with BC and CO, and BC showed a positive correlation with CO and PM2.5. Additionally, pPAHs exhibited a positive correlation with BC and CO, suggesting an association with incomplete combustion. NO2 was negatively correlated with O3, formed by photochemical reactions in the atmosphere. The hourly concentration trends of NOx and SO2 coincided, potentially linked to emissions from non-industrial sources. Higher concentrations of benzene, BC, PM10, pPAHs, NO2, CO, and SO2 were observed during commute times. PM10 concentrations in the fall exceeded the daily national guideline of 100 μg/m3 due to long-range atmospheric transport from China. Despite their relatively low concentrations, acetaldehyde & ethylene oxide, acrylonitrile, and 1,3-butadiene posed significant cancer and non-cancer risks. The findings of this study highlight that the levels and patterns of HAPs in Seoul are mainly influenced by local sources (e.g., solvents, vehicular exhaust, and combustion) as well as longrange atmospheric transport, and their order of priority varies based on levels and associated risks. Korean 한국대기환경학회 서울시 유해대기오염물질의 오염특성: 시계열 변화, 오염원 추정, 위해성평가 Pollution Characteristics of Hazardous Air Pollutants in Seoul: Temporal Variation, Source Identification, and Risk Assessment Article 10.5572/KOSAE.2024.40.1.84 2 한국대기환경학회지, v.40, no.1, pp.84 - 102 한국대기환경학회지 40 1 84 102 N kci ART003051436 BC Particle-bound PAHs Heavy metals SIFT-MS VOCs CAPs