Jun, Sungju Lee, Joo-Won Kim, Sung-Chul Oh, Soong Ju Jeong, Sohee 2024-04-24T07:32:51Z 2024-04-24T07:32:51Z 2024-03-21 2024-04 2050-7488 https://pubs.kist.re.kr/handle/201004/149689 While metastable metallic phases of group-VI transition metal dichalcogenide (TMDC) nanosheets exhibit intriguing and unprecedented characteristics, the development of reliable synthetic methodologies, particularly in direct solution-based synthesis, remains a challenge due to the lack of understanding of molecular leverage of the metal？ligand coordination geometry for obtaining metastable phases in two-dimensional (2D) TMDCs. Here, we describe an effective solution-based approach for directly synthesizing metastable metallic phases by unveiling the criterion for phase-selective formation, using appropriate ligands. Specifically, metallic 1T′-WSe2 and 1T-WS2 nanosheets were obtained with trioctylphosphine oxide, whereas 2H-WSe2 and 2H-WS2 nanosheets were formed using oleylamine. Spectroscopic analysis, including X-ray pre-edge absorption, revealed that phosphine oxide ligands (？O[double bond, length as m-dash]P) induce the distorted octahedral metal？ligand geometry, followed by the phase-selective formation of metallic 1T′ and 1T phases. Meanwhile, amine ligands (？NH2), accompanied by the trigonal prismatic metal？ligand geometry, exclusively lead to the production of 2H phases. This strategy was applied using hexadecylamine and triphenylphosphine oxide to produce 2H and 1T′ phases, respectively. As a proof-of-concept study, metallic 1T′-WSe2 shows enhanced hydrogen evolution activity with long-term durability. This strategy, controlling the metal？ligand coordination geometry by the choice of suitable ligands, offers a new guideline for securing metastable phases in 2D TMDCs. English Royal Society of Chemistry Unveiling the ligand-mediated phase engineering mechanism in two-dimensional transition metal chalcogenides through coordination geometry control Article 10.1039/d4ta00326h 1 Journal of Materials Chemistry A, v.12, no.13, pp.7522 - 7527 Journal of Materials Chemistry A 12 13 7522 7527 N scie scopus 001183842400001 2-s2.0-85187696463 Chemistry, Physical Energy & Fuels Materials Science, Multidisciplinary Chemistry Energy & Fuels Materials Science Article X-RAY 2H-MOS2 GROWTH WSE2