Hyun, Chang-Seok Eo, Joohwan Kwon, Ji Eon An, Byeong-Kwan 2024-08-08T02:00:35Z 2024-08-08T02:00:35Z 2024-08-08 2024-07 0039-7911 https://pubs.kist.re.kr/handle/201004/150385 1,4,5,8-tetrasubstituted dihyroanthracene-based triptycene trisquinones (TT) molecules, THAO-TT and tris(THAO)-TT, were synthesized by Diels-Alder reaction between TT and 1,4,5,8-tetrakis(hexyloxy)anthracene to produce the extended triptycene derivatives containing electron-accepting functionality. The prepared THOA-TT and tris(THOA)-TT exhibited excellent thermal stability owing to the rigid TT framework. The optical and redox properties of THOA-TT and tris(THOA)-TT were controlled by the homoconjugation between the benzoquinone units and the peripheral units through the connecting methine groups. English Marcel Dekker Inc. 1,4,5,8-tetrasubstituted dihydroanthracene-based triptycene trisquinones: Synthesis, structural, and physicochemical characterization Article 10.1080/00397911.2024.2381074 1 Synthetic Communications, v.54, no.15, pp.1263 - 1272 Synthetic Communications 54 15 1263 1272 N scie scopus 001278314700001 2-s2.0-85199753382 Chemistry, Organic Chemistry Article DYE Triptycene benzoquinone triptycene trisquinone homoconjugation through-space charge-transfer