Lee, Sangwoon Kim, Jaeyun Hong, Sung Woo Bang, Joona Park, Jong Hyuk 2024-10-04T01:30:21Z 2024-10-04T01:30:21Z 2024-10-02 2024-09 2214-9937 https://pubs.kist.re.kr/handle/201004/150710 As plastic waste from packaging continues to pose a serious threat to the environment, demand for naturally degradable packaging materials, such as biodegradable polymers, is increasing. However, packaging materials derived from biodegradable polymers often lack the mechanical and barrier properties required to replace conventional plastics. To address this issue, we propose an all-dry chemical engineering process to prepare high-performance biodegradable polymer composites incorporating cellulose nanofiber (CNF). Mechanochemistry (MC) is emerging as an effective method to induce chemical reactions between components using mechanical force under dry conditions. Through the MC process, we silanize CNFs and facilitate their chemical interaction with polybutylene succinate (PBS) matrix. This approach resolves the long-standing problem of CNF aggregation without using compatibilizers or solvents. The resulting PBS composite containing 3 wt% CNF exhibits improved mechanical and barrier properties comparable to polyethylene terephthalate, attributed to the formation of a uniform CNF network. Furthermore, its transparency and biodegradability demonstrate promising potential for replacing conventional packaging materials. Consequently, our study can offer a pathway to high-performance packaging materials based on biodegradable polymers, achieved through an environmentally and economically sustainable all-dry process. This contribution aligns with global efforts aimed at minimizing environmental damage from packaging waste. English Elsevier BV All-dry chemical engineering for high-performance packaging materials based on biodegradable polymer composites Article 10.1016/j.susmat.2024.e01118 1 Sustainable Materials and Technologies, v.41 Sustainable Materials and Technologies 41 N scie scopus 001319165800001 2-s2.0-85204071390 Green & Sustainable Science & Technology Energy & Fuels Materials Science, Multidisciplinary Science & Technology - Other Topics Energy & Fuels Materials Science Article POLY(BUTYLENE SUCCINATE) CELLULOSE NANOCRYSTALS MECHANICAL-PROPERTIES BEHAVIOR MECHANOCHEMISTRY NANOCOMPOSITES REINFORCEMENT BARRIER IMPACT SILANE Mechanochemistry Biodegradable polymer composites Cellulose nanofiber High-performance packaging materials All-dry chemical engineering