Altin, Emine Moeez, Iqra Kwon, Eunji Bhatti, Ali Hussain Umar Yu, Seungho Chung, Kyung Yoon Arshad, Muhammad Harfouche, Messaoud Buldu, Murat Altundag, Sebahat Bulut, Fatih Sahinbay, Sevda Altin, Serdar Ates, Mehmet Nurullah 2024-10-26T07:00:33Z 2024-10-26T07:00:33Z 2024-10-25 2024-12 1613-6810 https://pubs.kist.re.kr/handle/201004/150870 Herein, P2-type layered manganese and ruthenium oxide is synthesized as an outstanding intercalation cathode material for high-energy density Na-ion batteries (NIBs). P2-type sodium deficient transition metal oxide structure, Na0.67Mn1-xRuxO2 cathodes where x varied between 0.05 and 0.5 are fabricated. The partially substituted main phase where x = 0.4 exhibits the best electrochemical performance with a discharge capacity of approximate to 170 mAh g(-1). The in situ X-ray Absorption Spectroscopy (XAS) and time-resolved X-ray Diffraction (TR-XRD) measurements are performed to elucidate the neighborhood of the local structure and lattice parameters during cycling. X-ray photoelectron spectroscopy (XPS) revealed the oxygen-rich structure when Ru is introduced. Density of States (DOS) calculations revealed the Fermi-Level bandgap increases when Ru is doped, which enhances the electronic conductivity of the cathode. Furthermore, magnetization calculations revealed the presence of stronger Ru & horbar;O bonds and the stabilizing effect of Ru-doping on MnO6 octahedra. The results of Time-of-flight secondary-ion mass spectroscopy (TOF-SIMS) revealed that the Ru-doped sample has more sodium and oxygenated-based species on the surface, while the inner layers mainly contain Ru-O and Mn-O species. The full cell study demonstrated the outstanding capacity retention where the cell maintained 70% of its initial capacity at 1 C-rate after 500 cycles. English Wiley - V C H Verlag GmbbH & Co. Revealing the Role of Ruthenium on the Performance of P2-Type Na0.67Mn1-xRuxO2 Cathodes for Na-Ion Full-Cells Article 10.1002/smll.202406332 1 Small, v.20, no.50 Small 20 50 Y scie scopus 001326956800001 2-s2.0-85205390768 Chemistry, Multidisciplinary Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Physics, Applied Physics, Condensed Matter Chemistry Science & Technology - Other Topics Materials Science Physics Article LAYERED OXIDE BATTERIES ELECTRODE Na-ion batteries PT-type NaMnO2 Ru doped cathode